For the Rytm, the number of slices per chain must be divisible by 120, and as @orionka said you will also need to use the ‘spaced chain’ which will ensure all the slices are the same length.
E.g. for a gap of 8 on the sample start/end, you would get 15 samples in a chain.
You will see, the default options don’t have 15, so, Ctrl+Click on any one of the numbered options to enter your own custom number, [15], then create spaced chains.
The Rytm (and model:samples) don’t have a slice grid, so a bit of math is necessary unfortunately.
And there’s a list of all the keyboard shortcuts here.