On the Octatrack, if you want to load samples into a machine on a track, you first have to fill the sample slot list with samples.
There is one sample slot list for Flex Machines and one for Static Machines.
Flex Machines play samples from ram, Static Machines stream from the cf card.
Both sample slot liste are per project, so in all 16 banks in a project, you have access to those samples.
One very important concept of Octatracks structure are parts.
Parts can be compared to kits on other Elektron machines.
Each bank has four parts.
One part is always active.
A part contains which machines are assigned to which tracks, which samples are loaded in those machines, which fx are assigned on tracks + all the parameters and settings of those tracks and fx, also midi track settings and 16 scenes.
So when you make changes on a pattern, that is linked to a specific part, the parameters/settings on all other patterns, that use this part will also change.
If you want to use a new sample in a track, you don‘t necessarily have to use a new part, though.
There‘s also sample locks (change sample on a per step basis) and slices.
It‘s really best to read the user manual and Merlins Guide as already suggested.