Whilst RCA connectors can never be used to make a balanced connection and TRS connectors definitely can be used, balanced connection between two devices depends on one device having balanced outputs and one device having balanced inputs.
The advantage of a balanced connection is to do with noise reduction and is normally only necessary when using long cable runs.
I doubt if any of the Volcas have balanced outputs and though the Rytm has balanced outputs it has unbalanced inputs. Using RCA connectors should not make any difference as long as they are fully serviceable.